EXXON CO. U.S.A. -- EXXON UNLEADED GASOLINE -- 9130-00-148-7014
===================== Product Identification ===================== Product ID:EXXON UNLEADED GASOLINE MSDS Date:07/01/1985 FSC:9130 NIIN:00-148-7014 MSDS Number: BGWTD === Responsible Party === Company Name:EXXON CO. U.S.A. Address:800 BELL ST Box:2180 City:HOUSTON State:TX ZIP:77252-2180 Country:US Emergency Phone Num:713-870-6000 CAGE:KO279 === Contractor Identification === Company Name:EXXON CO. U.S.A. Address:800 BELL ST Box:2180 City:HOUSTON State:TX ZIP:77252-2180 Country:US CAGE:KO279 Company Name:EXXON COMPANY U.S.A. Address:Box:2180 City:HOUSTON State:TX ZIP:77252-2180 Country:US Phone:713-656-5949 / 713-656-3424 CAGE:29700 ============= Composition/Information on Ingredients ============= Ingred Name:GASOLINE CAS:8006-61-9 RTECS #:LX3300000 Other REC Limits:300 PPM OSHA PEL:300 PPM/500 STEL ACGIH TLV:300 PPM/500STEL;9192 Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <5% OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50 18,800 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO EYES,SKIN,RESPIRATORY TRACT AND DEPRESSES THE CENTRAL NERVOUS SYSTEM. CHRONIC OVER EXPOSURE MAY CAUSE LIVER,KIDNEY, OR CENTRAL NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:CONTAINS BENZENE;LISTED BY ALL THREE. ALSO,AN API STUDY FOUND LIVER CANCER IN MICE EXPOSED TO GASOLINE VAPORS. Effects of Overexposure:EYE/SKIN CONTACT:TRANSITORY IRRITATION. INHALED:RESPIRATORY IRRITATION,CENTRAL NERVOUS SYSTEM DEPRESSION INCLUDING,EUPHORIA,HEADACHE,DIZZINESS,DROWSINESS,FATIGUE,TREMORS,CO NVULSIONS,NAUSEA,VOMITING,DI ARRHEA,LOSS OF CONSCIOUSNESS AND FINALLYDEATH. INGESTED:G/I IRRITATION,PLUS SYMPTOMS SIMILAR TO THOSE UNDER "INHALED". Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN CONDITIONS OR IMPAIRED LIVER,KIDNEY FUNCTION MAY BE AGGRAVATED BY THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING;LAUNDER BEFORE REUSE. INHALED:REMOVE TO FRESH AIR.RESUSCITATE OR GIVE OXYGEN AS NEEDED. GET MEDICAL CARE. INGESTE D:GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING. IF VOMITING OCCURS,MINIMIZE ASPIRATION HAZARD. ===================== Fire Fighting Measures ===================== Flash Point:-36F Autoignition Temp:Autoignition Temp Text:853F Lower Limits:1.3 Upper Limits:7.6 Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM,WATER FOG. WATER MAY BE INEFFECTIVE,AS PRODUCT WILL FLOAT AND MAY SPREAD FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IN ENCLOSED AREAS. WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR,ACCUMULATING IN LOW AREAS, TRAVELING ALONG GROUND AND MAY FLASH BACK FROM DISTANT IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. ISOLATE AREA. USE PROTECTIVE EQUIPMENT A NECESSARY. STOP LEAK AND CONTAIN SPILL. DIKE AS NEEDED TO KEEP SPILL FROM DRAINS,WATER WAYS ETC. WATER FOG MAY BE USED TO REDUCE VA PORS & PERSONAL HAZARD. REPORT SPILL PERLAW. Neutralizing Agent:NONE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,ISOLATED,WELL VENTILATED AREA. KEEP IGNITION SOURCES AWAY. GROUND CONTAINERS TO PREVENT STATIC DISCHARGE DURING TRANSFERS. Other Precautions:FIRE AND EXPLOSION ARE THE ACUTE HAZARDS OF THIS PRODUCT. TAKE EXTRAORDINARY STEPS TO PREVENT THEM. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF NEEDED,USE NIOSH/MSHA RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE OR PREFERRABLY,A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR OR SELF CONTAINED BREATHING APPARATUS. Ventilation:USE EXPLOSION PROOF VENTILATION EQUIPMENT TO MAINTAIN EXPOSURE BELOW PEL/TLV. Protective Gloves:IMPERVIOUS RUBBER OR POLYMER. Eye Protection:SAFETY GLASSES,OR SPLASH GOGGLES. Other Protective Equipment:SAFETY SHOWER/EYE WASH. WORK CLOTHING AS NEEDED TO PROTECT FROM PROLONGED/REPEATED CONTACT. Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. MINIMIZE ALL CONTACT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:=21.1C, 70.F B.P. Text:70-440F Melt/Freeze Pt:<-38.C, -36.4F Vapor Density:3.5 (AIR) Spec Gravity:0.72-0.76 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR,COLORLESS TO STRAW YELLOW LIQUID,GASOLINE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:HEAT,SPARKS AND OTHER IGNITION SOURCES,VAPOR ACCUMULATIONS. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. PRODUCT QUALIFYS AS IGNITABLE WASTE AND CANNOT BE LANDFILLED. IF RECOVERY OR RECYCLE ARE UNACCEPTABLE, INCINERATION MAY BE ACCEPTABLE DISPOSAL METHOD. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.