EXXON -- EXXON OFF ROAD DIESEL 2, 072735-00786 -- 9140-00N073108
===================== Product Identification ===================== Product ID:EXXON OFF ROAD DIESEL 2, 072735-00786 MSDS Date:01/17/1995 FSC:9140 NIIN:00N073108 MSDS Number: CDWTX === Responsible Party === Company Name:EXXON Box:2180 City:HOUSTON State:TX ZIP:77252-2179 Country:US Info Phone Num:713-656-3424 Emergency Phone Num:713-656-3424 CAGE:IO892 === Contractor Identification === Company Name:EXXON Box:2180 City:HOUSTON State:TX ZIP:77252-2180 Country:US Phone:713-656-3424 CAGE:IO892 Company Name:EXXON COMPANY U.S.A. Address:Box:2180 City:HOUSTON State:TX ZIP:77252-2180 Country:US Phone:713-656-5949 / 713-656-3424 CAGE:29700 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM MID-DISTILLATE; (FUELS, DIESEL, NO. 2) CAS:68476-34-6 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:DYE CAS:84179-66-8 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:1-HEXANOL, 2-ETHYL-; (2-ETHYL HEXANOL) CAS:104-76-7 RTECS #:MP0350000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ANILINE (SARA 302/313) (CERCLA) CAS:62-53-3 RTECS #:BW6650000 OSHA PEL:S, 5 PPM ACGIH TLV:S, 2 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPDAT:PROD AWAY FROM IGNIT SOURCES, SUCH AS HEAT, SPKS, PILOT LIGHT, STATIC ELECTRICITY, & OPEN FLAMES. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: ARE NOT RELEVANT FOR HUMANS. TOTAL GASOLINE EXPOS ALSO PRDCED LIVER TUMORS. IMPLICATION FOR (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:HUMANS HAS NOT BEEN DETERM. MAY ALSO AFFECT NERV SYS. LOW ORDER TOX, BUT MINUTE AMTS ASPIR INTO LUNGS MAY (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:CAUSE MILD TO SEV PULM INJURY & POSS DEATH. INCR INCIDENCE OF LUNG CANCER. FOR MORE SPECIFIC INFO CONT NEHC. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:PRESS INJECTION MAY BE MINIMAL/ABSENT, EARLY SURGICAL TREATMENT W/IN FIRST FEW HOURS MAY (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:SIGNIFICANTLY REDUCE ULTIMATE EXTENT OF INJURY. INHAL:OVEREXP MAY CAUSE GASPING, NAUS & DISORIENTATION. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:VAP PRESS IS VERY LOW. VAP INHAL UNDER AMBIENT CNDTNS IS NORMLY NOT PROBLEM. IF OVERCOME BY VAP FROM HOT (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:PROD, REMOVE FROM EXPOS & CALL PHYS IMMED. IF BRTHG IS IRREGULAR/HAS STOPPED, START RESUSCITATION, ADMIN(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:OXYG, IF AVIAL. INGEST:DO NOT INDUCE VOMITING; CALL A PHYSICIAN IMMEDIATELY. RTECS #:9999999ZZ Ingred Name:SPILL PROC:ASSURE CONFORMITY W/APPLIC GOVT REGS. OBSERVE PRECAUTIONS. FOR MORE SPECIFIC INFORMATION CONT NEHC . RTECS #:9999999ZZ Ingred Name:OTHER PREC:OR RPTD CONT W/SKIN. "EMPTY" CNTNRS RETAIN RESIDUE (LIQUID &/OR VAPOR) & CAN BE DANGEROUS. DO NOT (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:PRESSURIZE, CUT, WELD,BRAZE, SOLDER, DRILL, GRIND/EXPOSE SUCH CNTNRS TO HEAT, FLAME, SPKS, STATIC ELEC, (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:OR OTHER SOURCES OF IGNIT; THEY MAY EXPLODE & CAUSE INJURY/DEATH. DO NOT ATTEMPT TO CLEAN SINCE RESIDUE(ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:IS DFCLT TO REMOVE. "EMPTY" DRUMS SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED & PROMPTLY RETURNED TO (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:DRUM RECONDITIONER. ALL OTHER CNTNRS SHOULD BE DISPOSED OF IN ENVIR SAFE MANNER & I/A/W GOVT REGS. FOR (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:WORK ON TANKS REFER TO OCCUP SFTY & HLTH ADMIN REGS, ANSI Z49.1, & OTHER GOVT & INDUST REFERENCES (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:PERTAINING TO CLEANING, REPAIRING, WELDING/OTHER CONTEMPLATED OPERATIONS. RTECS #:9999999ZZ Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD . RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT:REMOVE CONTAMD SHOES & THOROUGHLY CLEAN BEFORE REUSE; DISCARD IF OIL-SOAKED. CLEANSE SKIN THORO (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:AFTER CONT, BEFORE BREAKS & MEALS & AT END OF WORK PERIOD. PROD IS READILY REMOVED FROM SKIN BY WATERLESS(ING 25) RTECS #:9999999ZZ Ingred Name:ING 24:HAND CLEANERS FOLLOWED BY WASHING THOROUGHLY WITH SOAP AND WATER. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) >5 G/KG BODY WT Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:HUMAN HLTH RISKS MAY VARY FROM PERSON TO PERSON. EXPOS TO LIQS, VAPS, MISTS/FUMES SHOULD BE MINIMIZED. ACUTE:SKIN:DRY & DEFAT, IRRIT & DERM. INHAL:IRRITATING TO EYES & RESP TRACT, HDCH, DIZZ, ANESTH, DROW, UNCON, CNS EFTS, INCL DEATH. EYES:IRRITATION. CHRONIC:SKIN TUMORS &/OR SKIN CANCER. WASHING SKIN(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:W/SOAP & WATER BETWEEN APPLIC GREATLY REDUCES TUMOR FORMATION IN ANIMALS. CONTAINS LIGHT HYDROCARB COMPONENTS. LIFETIME STUDIES BY AMERICAN PETRO INSTITUTE HAVE SHOWN KIDNEY DMG & KIDNEY CANC ER CAN OCCUR IN MALE RATS AFTER PRLNGD INHAL EXPOS @ ELEVATED CONCS OF TOTAL GASOLINE. RAT KIDNEY TUMOR RSLTS (ING 6) Medical Cond Aggravated by Exposure:PETROLEUM SOLVENTS/PETROLEUM HYDROCARBONS - SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/CLEAR WATER FOR @ LST 15 MINS/UNTIL IRRIT SUBSIDES. IF IRRIT PERSISTS, CALL PHYS. SKIN:REMOVE ANY CONTAMD CLTHG & WASH SKIN W/SOAP & WATER. LAUNDER/DRY-CLEAN CLTHG BEFORE REUSE. IF PROD IS INJECTED INTO/UNDER SKIN/INTO ANY PARTOF BODY, REGARDLESS OF APPEARANCE OF WOUND/ITS SIZE, INDIVIDUAL SHOULD BE EVALUATED IMMED BY PHYS AS SURGICAL EMER. EVEN THOUGH INITIAL SYMPS FROM HIGH (ING 9) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:134F,57C Lower Limits:0.9% Upper Limits:7% Extinguishing Media:FOAM, WATER SPRAY(FOG), DRY CHEM, CARBON DIOXIDE & VAPORIZING LIQUID. FOR MORE SPECIFIC INFORMATION CONT NEHC . Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER MAY BE INEFTIVE, BUT WATER SHOULD BE USED TO KEEP FIRE-EXPOS CNTNRS COOL. IF LEAK/SPILL HAS IGNITED, (SUPDAT) Unusual Fire/Explosion Hazard:LIQ IS VOLAT & GIVES OFF INVISIBLE VAPS. EITHER LIQ/VAP MAY SETTLE IN LOW AREAS/TRAVEL SOME DIST ALONG GROUND/SURF TO IGNIT SOURCES; THEY MAY IGNITE (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF & ELIM IGNIT SOURCES. KEEP PEOPLE AWAY. RECOVER PROD. ADD SUITABLE ABSORB. MINIMIZE BRTHG VAPS & SKIN CONT. VENTILATE. KEEP OUT OF SEWERS & WATERCOURSES. ADVISE AUTH IF ENTERED/MAY ENTER SEWE RS, WATERCOURSES/EXTENSIVE LAND AREAS. (ING 14) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNRS CLSD WHEN NOT IN USE. DO NOT STORE NEAR HEAT, SPARKS, FLAME/STRONG OXIDANTS. IN ORDER TO PVNT FIRE/EXPLOS HAZARDS, USE APPROP EQUIPMENT. Other Precautions:INFO ON ELEC EQUIP APPROP FOR USE W/THIS PROD MAY BE FOUND IN LATEST EDITION OF NATL ELEC CODE (NFPA-70). THIS DOCUMENT IS AVAIL FROM NFPA, BATTERYMARCH PARK, QUINCY, MASSACHUSETTS 02269. MINIMIZE BRT HG VAP, MIST/FUMES. AVOID PRLNGD(ING 15) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPRVD SUPPLIED-AIR RESPIRATORY PROTECTION IN CONFINED OR ENCLOSED SPACES, IF NEEDED. Ventilation:VENT SUFFICIENT TO PREVENT EXCEEDING REC EXPOSURE LIMIT/BUILDUP OF EXPLO CONCS OF VAPOR IN AIR. Protective Gloves:CHEMICAL-RESISTANT GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 22) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . CHEM-RESIST APRON, IMPERVIOUS CLOTHING. Work Hygienic Practices:OBSERVING GOOD WORK PRACTICES & PERSONAL HYGIENE PROC. REMOVE CONTAMD CLTHG; LAUNDER/DRY-CLEAN BEFORE RE-USE. (ING 23) Supplemental Safety and Health PH:ESSNTLY NEUT. APPEAR/ODOR:HYDROCARB ODOR. FIRE FIGHT PROC:USE WATER SPRAY TO DISPERSE VAPS & TO PROTECT MEN ATTEMPTING TO STOP LEAK. WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOS. MINIMIZ E BRTHG OF GASES, VAP, FUMES/DECOMP PRODS. CONT NEHC FOR MORE SPECIFIC INFO . EXPLO HAZ:OR EXPLODE. KEEP (ING 5) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>320F,>160C Melt/Freeze Pt:M.P/F.P Text:-0F,-18C Vapor Pres:<1 @ 20C Vapor Density:>5 Spec Gravity:0.86 pH:SUPDAT Evaporation Rate & Reference:0.02 (N-BUTYL ACETATE =1) Solubility in Water:NEGLIGIBLE; <0.1% Appearance and Odor:CLEAR LIQUID, DYED (MAY BE RED, BLUE OR MIXTURE). FAINT PETROLEUM (SUPDAT) Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS SUCH AS LIQ CHLORINE, CONCENTRATED OXYG, SODIUM HYPOCHLORITE, CALCIUM HYPOCHLORITE, ETC. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE, SULFUR OXIDES, ALDEHYDES AND OTHER DECOMPOSITION PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.